Although no stainless steel grade is totally immune to chloride scc, the relative. Stress relieved samples were uniaxially prestrained to 5% and were loaded with nine levels of mgcl 2, investigating cl. Escc susceptibility depends on environmental factors. Stress corrosion cracking susceptibility of 304l substrate. It is considered resistant to pitting corrosion in water with up to about 400 mgl chlorides at ambient temperatures, reducing to. Corrosion resistance chloride stress cracking ak steel nitronic 19d stainless steel, like other duplex stainless steels, offers superior chloride stress corrosion cracking resistance relative to fully austenitic stainless steels like types 304 and 316. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. Ss304 grade aisi 304 stainless steel properties, composition. Type 444 is equivalent to type 304 in many corrosion environments and has lower coefficient of expansion and better thermal conductivity. The standard 304304l and 316316l grades are most susceptible. Through a loadfree testing in the boiling magnesium. Jan 14, 2020 the effect of the machininginduced residual stresses and microstructural changes on the stress corrosion cracking scc initiation in 304 austenitic stainless steel was investigated. This mode of attack is termed stress corrosion cracking scc.
Laboratory tests were conducted to investigate the stress corrosion cracking scc of 304l stainless steel used to construct the containment vessels for the storage of plutoniumbearing materials. For more information, please check 304 vs 316 stainless steel. Potential and strain rate effects in slow strain rate. It is less resistant than 304 304l to pitting and crevice corrosion in chloride environments. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353 k with relative humidity rh of. Pdf stress corrosion cracking of austenitic stainless. Pdf chloride induced stress corrosion cracking of type 304.
Their mixed microstructure provides improved resistance to chloride stress corrosion cracking in comparison to austenitic stainless steel types 304 and 316. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion. A great concern for the longterm integrity of canisters located near the coastline is chlorideinduced stress corrosion cracking of austenitic stainless steels 3,4,5. Therefore, the scc concerns for spent fuel storage canisters identified in a november 2004 presentation by nuclear and. Effects of temperature and humidity on atmospheric stress.
How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. In this case, the most fashion of failure mode in ss is present. Chloride stress corrosion cracking in austenitic stainless. Like all duplex stainless steels, ldx 2101 shows good resistance to chlorideinduced stress corrosion cracking scc. The drip procedure from the standard test method for evaluating the influence of thermal insulation on external stress corrosion cracking tendency of austenitic stainless steel astm c 69295a was used to research the effect of halogens and inhibitors on the external stress corrosion cracking escc of type 304 stainless steel as it applies to nuclear regulatory commission. Their chemical composition, mechanical properties, weldability and corrosionoxidation resistance provide the best allround performance stainless. Summary of available data for estimating chlorideinduced scc. Chloride stress corrosion cracking in austenitic stainless steel.
Stress corrosion cracking facts and how to reduce the risk. Stress corrosion cracking scc of austenitic stainless steels has been a known failure mode for more than 80 years and it. It has general corrosion resistance similar or better than alloys 304l and 316l but with yield strength nearly double that of austenitic stainless steels. Tp304 ss and tp316 ss can occur when water containing chloride is present underneath insulation, external metal skin temperature exceeds approximately 50 c, and there is no surface protection or when the protective coating e. Aisi 304l is the low carbon version of 304 stainless steel, aisi 316 is better than grade 304 in certain properties, corrosion resistance and heat resistance, etc. Aisi 304 stainless steel ss is one of the candidate materials used for dry storage canisters of spent nuclear fuel as an interim storage measure before final disposal 1,2. Scc will occur when stainless steels are subjected to tensile stress, while in contact with solutions containing chlorides. In all cases of failure by stress corrosion cracking, the following three factors must be present. Scc occurs when susceptible material under the stress is exposed to a specific environment such as corrosive environment.
The normal solubility of o2 in water at room to moderate temperatures e. The standard 304 304l and 316316l grades are most susceptible. Loto department of chemical and metallurgical engineering, tshwane university of technology, pretoria, south africa received dec 2012, revised 1 feb 20, accepted 1 feb 20 email address. Although 317l is somewhat more resistant to stress corrosion cracking than 304 304l stainless steels, because of its higher molybdenum content, it is still susceptible. We examined the effects of temperature and humidity on escc experimentally.
It is less resistant than 304304l to pitting and crevice corrosion in chloride environments. Considered resistant to potable water with up to about 200mgl chlorides at ambient temperatures, reducing to about 150mgl at 60c. Excellent in a wide range of atmospheric environments and many corrosive media. The datasheet and specification are summarized in the following tables including. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. The typical crack morphology for chloride stress corrosion cracking consists of branched transgranular cracks. Samples were subject to 60 mpa stress, 90 c at 70% relative humidity, for 480 h. Assessing the risk of underdeposit chlorideinduced stress. Chloride induced stress corrosion cracking of type 304 and. Aisi 304 grade stainless steel uns s30400 aisi 304 stainless steel uns s30400 is the most commonly used material in stainless steels, and is usually purchased in an annealed or cold worked state.
Chloride stress corrosion cracking cscc of aisi 304 austenitic stainless steel are the most important corrosion processes that affect the performance of this stainless steel. Although no stainless steel grade is totally immune. Austenitic stainless steel may be susceptible to chloride stress corrosion cracking cscc. Stress corrosion cracking scc in nonsensitised types 304l and 316l stainless steels in. In general, austenitic stainless steels are subject to chloride stress corrosion cracking in halide service. It is subject to pitting and crevice corrosion in warm chloride environments, and to stress corrosion cracking above 60 c approximate. External chloride stress corrosion cracking ecscc of insulated austenitic stainless steels e. Pdf chloride stress corrosion cracking scc of type 304 and 304l. Types 304, 304l and 304h are the most versatile and widely used of all the stainless steels. Pdf chloride induced stress corrosion cracking of type 304 and. Its duplex microstructure and low nickel and high chromium contents also allows duplex 2304 to demonstrate improved stress corrosion resistant properties compared to 304 and 316. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Effects of fluoride and other halogen ions on the external.
The residual stress was measured with an xray diffractometer, and the microstructural changes were characterized by the electron backscatter diffraction. Influence of high temperature on corrosion behavior of 304. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. Fecl 3 droplets with varying chloride deposition densities 1. The oxide originated on surface could act as a crack initiator and a crack propagation would progress along grain boundaries and particularly along tunnel of pores.
Pitting corrosion evaluation of austenitic stainless steel type 304 in acid chloride media r. Pitting and stress corrosion cracking studies on aisi type 316n. It is an austenitic, corrosion resistant steel with excellent strength, toughness, fabrication characteristics and weldability. Chloride stress corrosion cracking in austenitic stainless steel chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. This results because of their similarity in nickel content. Chloride stress corrosion cracking and 316 stainless steel moltenmetal chemical 20 jul 11 07. Threshold temperature for stress corrosion cracking of. The low carbon version, 304l, may be required for full corrosion resistance when thicker sections are welded. The stress corrosion cracking scc of a commercial austenitic stainless steel type 304 was investigated as functions of chloride concentration, chromate concentration and test temperature under a constant applied stress condition in 0. Chloride induced stress corrosion cracking of type 304 and 304l stainless steels in air masami mayuzumi, taku arai and koichiro hide. Scc is a form of corrosion that occurs in nearly all alloys, including the grades of stainless steel commonly used in brewery equipment types 304, 304l, 316, and 316l.
Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. While the surveyed studies all explore scc of austenitic stainless steels under atmospheric. When stainless steels are fully immersed, it is rare to see chloride stress corrosion cracking at temperatures below 60 c 150 f. Selected properties of the halides and overview of observed modes of. Potential and strain rate effects in slow strain rate stress. Threshold temperature for stress corrosion cracking of duplex. This paper described the mechanism of chlorideinduced stress corrosion cracking of oil tube as a result of. A precursor of stress corrosion cracking in chloride bearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Stress corrosion cracking, stainless steel, chloride, low. Grade 304 stainless steel is excellent in a wide range of atmospheric environments and many corrosive media.
Table 8 chloride stress cracking resistance alloy hours to failure. The occurrence of pitting corrosion, crevice corrosion, atmospheric chlorideinduced stress corrosion. Figure 1 shows the cracking that occurred on a 6mo super austenitic stainless steel n08367 exposed to 0. Chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Investigation of stress corrosion cracking initiation in. Stp727 potential and strainrate effects in slow strainrate stress corrosion cracking of type 304 stainless steel in 35 percent magnesium chloride at 120c. High residual or applied stress, temperature above 6571c 150160f and chlorides increase the likelihood of cscc. There is a synergistic relationship between dissolved oxygen and the chloride level. Localized corrosion and stress corrosion cracking of stainless steels.
Chloride stress corrosion cracking and 316 stainless steel. For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater jacketed pipes carrying molten chocolate in the food industry. Chlorideinduced transgranular stress corrosion cracking of. Therefore, standard grades such as 304304l and 316316l are very. Scc propagation rates for atmospheric corrosion of 304ss. Stress corrosion cracking of type 304 austenitic stainless. Chlorideinduced stress corrosion cracking of 316 stainless. Prior cold deformation of the structure under load increases the risk of stress corrosion cracking. The combination of tensile stress and a specific corrosive environment can crack stainless steels. The material used in the present study is 304 stainless steel, the chemical composition of it is shown in table i. Specifications type 444 stainless steel sheet and strip is covered by the following.
Austenitic stainless steels are widely used as structural materials for chemical and power plants. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Typical appearance of chloride stress corrosion cracking. Atmospheric corrosion testing has proven 3cr12 offers 250 times the life of unpainted mild steel in moderate marine environments. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. For example, chloride stress corrosion cracking of austenitic stainless steel.
Corrosion resistance stress corrosion cracking 2205 is a cost effective solution for many applications where 300 series stainless steels are susceptible to chloride stress corrosion cracking scc. Intergranular stress corrosion cracking was observed. Three underlying factors must be present to cause scc. Duplex grades are usually divided into three subgroups based on their corrosion resistance. It is difficult to control the temperature, while changing pipe material or eliminating residual stresses associated with welding and forming the pipework is costly and. Because ss 304 contains 18% chromium cr and 8% nickel ni, its also known as 188 stainless steel. Type 304 uns s30400 austenitic stainless steel was exposed for 6 months under elastic 0.
Subject to pitting and crevice corrosion in warm chloride environments, and to stress corrosion cracking above about 60c. F kjkg it has superior chloride stress corrosion cracking resistance to types 304 and 316. Keywords strain, temperature, chloride stress corrosion cracking scc, corrosion fatigue, austenitic stainless steel, type 304l stainless steel, crack density. Although 317l is somewhat more resistant to stress corrosion cracking than 304304l stainless steels, because of its higher molybdenum content, it is still susceptible. The effect of salt loading on chlorideinduced stress corrosion cracking in 304 l was studied at atmospheric pressure. Conventional stainless steels such as 304l and 316l are susceptible to chloride stress corrosion cracking ssc under certain conditions. Chloride stress corrosion cracking clscc is one the most common reasons why.
Three general classifications are used to identify stainless steels. Methods of minimizing chloride stress corrosion cracking. As its name suggests, scc takes the form of a network of cracks that eventually will lead to sudden, catastrophic failure in your tanks. The effect of salt loading on chloride induced stress corrosion cracking in 304 l was studied at atmospheric pressure.
Transgranular stress corrosion cracking of 304l stainless. The effect of salt loading on chlorideinduced stress. Effects of marine environments on stress corrosion cracking. Pitting corrosion evaluation of austenitic stainless steel. Stress corrosion cracking in a brewery paul mueller company. Pitting and stress corrosion cracking studies on aisi type 316n stainless steel weldments. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. Increasing nickel content above 18 to 20% or the use of duplex, or ferritic stainless steels improves resistance to cscc. Effects of marine environments on stress corrosion. The effect of the machininginduced residual stresses and microstructural changes on the stress corrosion cracking scc initiation in 304 austenitic stainless steel was investigated. Design guidelines for the selection and use of stainless steel nidl distributed by. Alloy 317l austenitic stainless steel plate sandmeyer steel.
Grade 304 is the most commonly used stainless steel. The observed crack propaga tion is the result of the combined and synergistic interaction of mechanical stress and corrosion re actions. The type 321 austenitic stainless steel is susceptible to stress corrosion cracking scc in halides similar to type 304 stainless steel. Chloride stress corrosion cracking inspectioneering.
Like all duplex stainless steels, ldx 2101 shows good resistance to chloride induced stress corrosion cracking scc. Chloride induced stress corrosion cracking of 316 stainless steel oil tube hi everybody, today, i would like to show my case study to you. Reference is often made to stainless steel in the singular sense as if it were one material. Stress corrosion cracking of sensitized type 304 stainless. Yamazaki, 1996, 1997 potential of type 304 stainless steel in cl. Engelberg, toward understanding the effects of strain and chloride deposition density on atmospheric chlorideinduced stress corrosion cracking of type 304 austenitic stainless steel under mgcl2 and fecl3. External stress corrosion cracking escc by sea salt particles can occur in these plant component materials. With a nickel content of 25%, 904l has proven to be a good alternative to most conventional stainless steels. Sensitized austenitic stainless steel suffers stress corrosion cracking scc in solutions of. Toward understanding the effects of strain and chloride.